Water-based UV curable hybrid urethane-acrylates formed by acid–base interaction between tertiary amine containing polyurethane and acrylic acid for photocoating and ink applications
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Water-based UV curable hybrid urethane-acrylates formed by acid–base interaction between tertiary amine containing polyurethane and acrylic acid for photocoating and ink applications
Water-based UV curable hybrid urethane-acrylates formed by acid–base interaction between tertiary amine containing polyurethane and acrylic acid for photocoating and ink applications
Dsouza, R. F., & Parthiban, A. (2024). Water‐based <scp>UV</scp> curable hybrid urethane‐acrylates formed by acid–base interaction between tertiary amine containing polyurethane and acrylic acid for photocoating and ink applications. Journal of Applied Polymer Science. Portico. https://doi.org/10.1002/app.55193
Abstract:
AbstractUrethane acrylate hybrids are commonly used in polyurethane dispersions (PUD). PUDs are key ingredients in UV curing applications and UV curing is widely used in coatings and inks. The preparation of PUDs involves many volatiles in the form of solvents and reagents that are also carried over in the UV curing step. This article reports a process, which totally eliminates these volatile components and additionally introduces many flexibilities. The process involves acid–base interaction between tertiary amine containing polyurethane and acidic vinyl monomer like acrylic acid forming polyurethane‐acrylate (PU‐AA) hybrids in water. The developed process also overcomes the prepolymer and “endcapping” approaches used in the preparation of PUDs that restrict the molecular weight of polyurethanes. Simultaneously, because of the prevalence of large number of vinyl components in the polymer backbone through the acid–base interaction, it functions as a multifunctional acrylate similar to the reactive diluents used in UV curing applications. Thus, it helps to increase the cross‐linking density of the UV cured substrates. In general, high crosslinking density helps to improve characteristics like hardness, scratch, solvent and stain resistance of coated substrates. The process has been demonstrated to form transparent and opaque coated substrates and cured inks. This development potentially helps to shift the process from an industrial activity to do‐it‐yourself domain and has implications for the development of components for 3D printing sustainably.
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Funding Info:
This research / project is supported by the A*STAR - Environmentally Friendly Specialty Products Programme
Grant Reference no. : 1528000045
Description:
This is the peer reviewed version of the following article: Dsouza, R. F., & Parthiban, A. (2024). Water‐based UV curable hybrid urethane‐acrylates formed by acid–base interaction between tertiary amine containing polyurethane and acrylic acid for photocoating and ink applications. Journal of Applied Polymer Science. Portico. https://doi.org/10.1002/app.55193, which has been published in final form at doi.org/10.1002/app.55193. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.