Single-pot conversion of tetrahydrofurfuryl alcohol into tetrahydropyran over a Ni/HZSM-5 catalyst under aqueous-phase condition

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Single-pot conversion of tetrahydrofurfuryl alcohol into tetrahydropyran over a Ni/HZSM-5 catalyst under aqueous-phase condition
Title:
Single-pot conversion of tetrahydrofurfuryl alcohol into tetrahydropyran over a Ni/HZSM-5 catalyst under aqueous-phase condition
Journal Title:
ChemCatChem
Publication Date:
04 April 2017
Citation:
Soghrati, E.; Choong, C. K. S.; Poh, C. K.; Kawi, S.; Borgna, A., Single-pot conversion of tetrahydrofurfuryl alcohol into tetrahydropyran over a Ni/HZSM-5 catalyst under aqueous-phase condition. ChemCatChem 2017, 9 (8), 1402-1408.
Abstract:
Ni‐based catalysts were examined in the hydrogenolysis of tetrahydrofurfuryl alcohol, resulting in the selective C−O bond cleavage to produce 1,5‐pentanediol, along with 1,2,5‐pentanetriol, which was detected for the first time under aqueous‐phase conditions. 70 % yield to tetrahydropyran was achieved using one‐pot conversion over bifunctional Ni/HZSM‐5 catalysts.
License type:
PublisherCopyrights
Funding Info:
This work was supported by the Singapore International Graduate Award (SINGA) scholarship of Agency for Science, Technology and Research (A*STAR).
Description:
This is the peer reviewed version of the following article: Soghrati, E.; Choong, C. K. S.; Poh, C. K.; Kawi, S.; Borgna, A., Single-pot conversion of tetrahydrofurfuryl alcohol into tetrahydropyran over a Ni/HZSM-5 catalyst under aqueous-phase condition. ChemCatChem 2017, 9 (8), 1402-1408, which has been published in final form at https://doi.org/10.1002/cctc.201601708. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.
ISSN:
1867-3880
1867-3899
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