Pd-Ce nanoparticles supported on functional Fe-MIL-101-NH 2 : an efficient catalyst for selective glycerol oxidation

Page view(s)
19
Checked on Mar 25, 2024
Pd-Ce nanoparticles supported on functional Fe-MIL-101-NH 2 : an efficient catalyst for selective glycerol oxidation
Title:
Pd-Ce nanoparticles supported on functional Fe-MIL-101-NH 2 : an efficient catalyst for selective glycerol oxidation
Journal Title:
Catalysis Today
Keywords:
Publication Date:
12 April 2016
Citation:
Li, X. H.; Tjiptoputro, A. K.; Ding, J.; Xue, J. M.; Zhu, Y. H., Pd-Ce nanoparticles supported on functional Fe-MIL-101-NH2 : an efficient catalyst for selective glycerol oxidation. Catalysis Today 2017, 279, Part 1, 77-83.
Abstract:
Metal organic framework Fe-MIL-101-NH2 was prepared at different reaction time. The morphology of the Fe-MIL-101-NH2 slightly changed following a longer reaction time; the crystal structure remained. Neocuproine ligand coordinating palladium complex has demonstrated high activity in selective glycerol oxidation towards 1,3-dihydroxyacetone (DHA). Neocuproine ligand was attached to MOF Fe-MIL-101-NH2 by forming an amide (CONH) bond in this work. The functional Fe-MIL-101-NH2 was used as catalyst supports to hold palladium and cerium nanoparticles. The resulting composite of the Pd-Ce/Fe-MIL-101NCHNeocuproine was found to be a high efficient catalyst in the selective oxidation conversion of glycerol to dihydroxyacetone in comparison with catalysts Pd/Fe-MIL-101NCHNeocuproine and Pt-Bi/C. The catalysts and products were analyzed by FT-IR, XRD, SEM, TEM and 1H, 13C NMR spectroscopy. In addition, the supported catalyst is recyclable with sustainable activity.
License type:
http://creativecommons.org/licenses/by-nc-nd/4.0/
Funding Info:
This work is supported by the SMART (Singapore-MIT Alliance for Research and Technology) Innovation grant and ICES, A*STAR.
Description:
ISSN:
0920-5861
Files uploaded:

File Size Format Action
fy16-009-pec-manu.pdf 2.51 MB PDF Open