Gowrisankar, S.; Seayad, J., AgONO-assisted direct C[BOND]H arylation of heteroarenes with anilines. Chemistry - A European Journal 2014, 20, (40), p 12754-1275.8.
Abstract:
A novel copper-catalyzed C[BOND]H arylation of heteroarenes with anilines by an in situ diazonium reaction is established by using silver nitrite (AgONO) as an unconventional nitrosating reagent under acid-free conditions. It provides a complementary approach for the C[BOND]H arylation of electron-rich heteroarenes with aromatic amines affording a variety of heterobiaryls in moderate to good yields.
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Funding Info:
This work was supported by the GSK–Singapore partnership for green and sustainable manufacturing.
Description:
This is the peer reviewed version of the following article: Gowrisankar, S.; Seayad, J., AgONO-assisted direct C[BOND]H arylation of heteroarenes with anilines. Chemistry - A European Journal 2014, 20, (40), p 12754-12758, which has been published in final form at https://dx.doi.org/10.1002/chem.201403640. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving.